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Efficient CoMoRu0.25Ox/NF nanoplate architectures for overall electrochemical water splitting
International Journal of Hydrogen Energy Số 94, năm 2022 (Tập 47, trang 39908-39916)
ISSN: 3603199
ISSN: 3603199
DOI:
Tài liệu thuộc danh mục:
Article
English
Từ khóa: Cobalt compounds; Molybdenum oxide; Nanostructures; Ruthenium compounds; Bifunctional electrocatalysts; Electrocatalytic activity; Electrochemicals; Hetero-interfaces; Long term stability; Nanoplates; Overall water splitting; Overpotential; Synthesised; Water splitting; Electrocatalysts
Tóm tắt tiếng anh
The development of inexpensive electrocatalysts with excellent electrocatalytic activity for the hydrogen and oxygen evolution reactions (HER and OER, respectively) has been challenging. In this study, we synthesized cobalt molybdenum ruthenium oxide with porous, loosely-assembled nanoplate morphology. The CoMoRu0.25Ox/NF electrocatalyst exhibited the highest electrocatalytic activity, requiring overpotentials of 230 and 78 mV for the OER and HER, respectively, to attain a current density of 10 mA cm−2; moreover, its long-term stability was outstanding. The electrocatalyst required a cell voltage of only 1.51 V for overall water splitting in an alkaline medium, which was lower than that required by many CoMo-based catalysts. © 2022 Hydrogen Energy Publications LLC